This seems to be related to Excel/XLS files, for some reason. If I delete (from Alfresco) the XLS files, it works fine. Adding them back in to the Site, it still works. So something related to the upgrade perhaps (this is a 3.2 site upgraded to 3.3g)? Not sure what to think but at least can pin it down to a file-type, and not Alfresco/webdav implementation as a whole….