Either you have to use NTLMV1 - there's a windows registry setting you need to change. Or the other work around is to run the windows domain controller on the same windows machine as alfresco.
The real solution to this mess is not to use NTLM at all. The current advice from Microsoft is to use kerberos instead.
You can manage CIFS authentication services from further versions. The recommended methods to configure, manage, and modify CIFS properties and parameters are by using manager.