I'm not aware of a way to prevent indexing of a specific file, but if you know what file it is, put a password on the file. That way transformation will fail (rather than halting the whole server). If needed, write the password in the description field so that those who needs to open can do so.
It would just be a workaround, and not a terribly good one, just thought that it may be worth having as an option.
Another would be to disable content transformations for all excel files until properly resolved. Have a look in content-services-context.xml to find out what beans to change/disable. Maybe comment out the bean <bean id="transformer.Poi", that way I think it will user OpenOffice instead. But you have to try this out.