The e-mail invitation can only be used one time so you will have to contact the Site Manager, the person who sent the e-mail invitation, and have them check to see if you really are a member in the Members section of the Site. If you are not listed in the People section of the Members page the Site Manager will need check to see if you are listed in the Pending Invites of the Members page. If you are listed in the Pending Invites your invitation will need to cancelled and a new invitation sent.